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An exothermic reaction, A → 213, takes place

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An exothermic reaction, A → 213, takes place adiabatically in a stirred-tank reactor. This liquid reaction occurs at constant volume in a 1000-gal reactor. The reaction can be considered to he first order and irreversible with the rate constant given by

k = 2.4 x 1015e-20.000/T (min–1)

where T is in oR.

(a) Using the information below, derive a transfer function relating the exit temperature T to the inlet concentration cAt. State all assumptions that you make,

(b) How sensitive is the transfer function gain K to the operating conditions? Find an expression for the gain in terms q, T, and cAi evaluate the sensitivities. (That is, ∂k/∂q, etc.)

Available Information

(i) Nominal steady-state conditions are:

T = 150 oF, cAi = 0.8 mol/ft3

q = 20 gal/min flow in and out of the reactor

(ii) Physical property data (or the mixture at the nominal steady state:

An exothermic reaction, A → 213, takes place

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